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Polyaluminium Chloride (PAC) in Textile & Dyeing Wastewater Treatment

Table of Contents

Why Textile & Dyeing Wastewater Is One of the Hardest to Treat

Textile and dyeing wastewater is well known for being highly colored, chemically complex, and unstable. This makes biological treatment alone ineffective and risky.

Textile wastewater treatment plant

Typical Characteristics

  • Extremely high chromaticity
    Reactive dyes, disperse dyes, sulfur dyes
  • High COD (often 2,000–10,000 mg/L)
    Dye auxiliaries, surfactants, sizing agents
  • Large pH fluctuations
    pH may shift from acidic to strongly alkaline
  • Poor biodegradability
    Many dye molecules resist microbial degradation

Because of these factors, chemical coagulation is mandatory, and PAC is one of the most reliable choices.

industrial dyeing wastewater treatment chemicals .

Why PAC Is Highly Effective for Dyeing Wastewater

Compared with alum or ferric salts, PAC offers clear advantages in color removal and COD reduction.

Key Advantages of PAC in Textile Applications

  1. Strong adsorption of dye molecules
    PAC hydrolyzes to form Al(OH)₃ colloids, which adsorb dye chromophores.
  2. Fast floc formation
    Suitable for high-throughput textile plants.
  3. Wide pH adaptability (pH 5–9)
    Reduces the need for heavy pH adjustment.
  4. Lower sludge volume
    Critical for textile plants with limited sludge disposal capacity.

How PAC Removes Color from Textile Wastewater

Decolorization Mechanism Explained

  1. Charge neutralization
    PAC neutralizes negatively charged dye molecules and colloids.
  2. Adsorption & sweeping
    Al(OH)₃ flocs “sweep” dye molecules out of solution.
  3. Floc separation
    Flocs are removed via sedimentation or DAF.

In many cases, color removal efficiency reaches 85–95% at the primary treatment stage.

Common Treatment Processes Using PAC in Textile Plants

1. Coagulation–Sedimentation (Basic Setup)

Best for:
Medium SS, moderate dye concentration

Typical results:

  • Color removal: 80–90%
  • COD reduction: 25–40%

2. PAC + DAF (Preferred for High Color)

Best for:
High dye concentration, light flocs

Advantages:

  • Faster separation
  • Smaller footprint
  • Stable effluent color

3. PAC + PAM Combination (Industry Standard)

PAC alone destabilizes dyes, but PAM strengthens flocs.

  • PAC: destabilization & adsorption
  • PAM: bridging & floc growth

This combination:

  • Reduces PAC dosage
  • Improves color consistency
  • Enhances sludge dewatering
PAC + PAM Combination

Typical PAC Dosage for Textile Wastewater

ParameterTypical Range
PAC dosage80–300 mg/L
PAM dosage1–5 mg/L
Optimal pH6.0–8.5

⚠️ Always confirm via jar testing due to dye variability.

Procurement Insights: How to Choose PAC for Textile Plants

When purchasing PAC for textile wastewater, buyers should focus on:

  • High basicity (≥60%) for better decolorization
  • Fast dissolution for automated dosing systems
  • Low insoluble content to prevent pipeline blockage

Conclusion

PAC is one of the most reliable chemical solutions for textile and dyeing wastewater treatment. Its strong decolorization ability, wide pH tolerance, and compatibility with PAM make it a preferred choice for textile plants aiming to meet discharge standards while controlling costs.

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